chem: Add reduction reactions

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eggy 2022-04-11 10:11:28 -04:00
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@ -669,6 +669,33 @@ $$\ce{R-X + C#N- -> R-C#N + X-}$$
### Reduction reactions
**Hydride reagents** include $\ce{LiAlH4}$ and $\ce{NaBH4}$, the former of which requires ether because it reacts violently with water. Always use $\ce{LiAlH4}$ unless specified otherwise.
**Aldehydes** can be reduced to **primary alcohols**.
$$\ce{aldehyde ->[LiAlH4, ether, then acid] 1^\circ alcohol}$$
**Amides** can be reduced to their **amines**, reacting twice such that the O pops off. The name is a simple `amide.replace("amide", "amine")`.
$$\ce{amide ->[LiAlH4, ether, then acid] amine}$$
**Carboxylic acids** can be reduced to **primary alcohols** with the $\ce{C=O}$ plopping off.
$$\ce{carboxylic acid ->[LiAlH4, ether, then acid] 1^\circ alcohol}$$
**Esters** can be reduced to **two primary alcohols** with each alcohol keeping an O and gaining an H to make OH.
$$\ce{ester ->[LiAlH4, ether, then acid] 1^\circ alcohol + 1^\circ alcohol}$$
**Nitriles** can be double reduced to **amines**.
$$\ce{nitrile ->[LiAlH4, ether, then acid] amine}$$
!!! warning
$\ce{LiAlH4}$ is required for this reaction.
### Retro-synthesis
### Simple polymers