From 739d9b8c44f114795e6c53e5a42c6bdccf400a61 Mon Sep 17 00:00:00 2001 From: eggy Date: Thu, 12 Nov 2020 20:02:57 -0500 Subject: [PATCH] chem: start hybridisation --- docs/sch3uz.md | 34 ++++++++++++++++++++++++++++++++++ 1 file changed, 34 insertions(+) diff --git a/docs/sch3uz.md b/docs/sch3uz.md index 6316be0..52bfb18 100644 --- a/docs/sch3uz.md +++ b/docs/sch3uz.md @@ -748,6 +748,40 @@ Please see [SL Physics#Uncertainty of gradient and intercepts](/sph3u7/#uncertai ## 11.3 - Spectroscopic identification of organic compounds +## 14.2 - Hybridisation + +Covalent bonds are formed by overlapping orbitals of different atoms. To do so, atoms may need to recombine/mix orbitals at the highest main energy level and redistribute electrons when forming these **hybrid orbitals**. This process is known as hybridisation. Orbitals of the same atom of different energies can overlap to form hybrid orbitals of **equal energy** between the energies of the atomic orbitals used, and the number of hybrid orbitals is equal to the number of atomic orbitals used. + +The resulting hybrid orbitals arrange themselves such that they follow the electron distributions and molecular shapes predicted by VSEPR. + +(Source: Kognity) + +Hybrid orbitals all must have exactly one electron in them. + +At the highest energy level, the order of orbitals used for hybridisation are s, p, and then d. As such, hybrid orbitals are named $s^np^nd^n$. The number of electron domains is equal to the number of hybrid orbitals. + +### sp3 hybridisation + +One s orbital and three p orbitals mix to form four sp3 orbitals, which will adopt a tetrahedral arrangement. + +(Source: Kognity) + +### sp2 hybridisation + +One s orbital and two p orbitals mix to form three sp2 orbitals, which will adopt a trigonal planar configuration. Note that the remaining p orbital remains unhybridised and is perpendicular to the planar shape. + +(Source: Kognity) + +(Source: Kognity) + +### Other hybridisations + +One s orbital and one p orbital mix to form two sp orbitals, which will arrange themselves in a linear configuration perpendicular to the unhybridised p orbitals. + +One s orbital, three p orbitals, and one d orbital mix to form five sp3d orbitals, which will arrange themselves in a trigonal bipyramidal configuration. + +One s orbital, three p orbitals, and two d orbitals mix to form six sp3d2 hybrid orbitals, which will arrange themselves in an octahedral configuration. + ## Designing a scientific investigation ### Scope