From 8a506393104393dcaf717fb07cf4b9ac3cd76182 Mon Sep 17 00:00:00 2001 From: eggy Date: Tue, 4 Jan 2022 21:56:32 -0500 Subject: [PATCH] chem: Introduce acids/bases --- docs/sch4uz.md | 42 ++++++++++++++++++++++++++++++++++++++++++ 1 file changed, 42 insertions(+) diff --git a/docs/sch4uz.md b/docs/sch4uz.md index 52cbfef..ac1a0d3 100644 --- a/docs/sch4uz.md +++ b/docs/sch4uz.md @@ -575,6 +575,48 @@ $$\Delta G = \Delta G^\circ + RT\ln Q$$ Therefore, at equilibrium: $\Delta G = -RT\ln K_c$ +## Acids and bases + +### Arrhenius theory + +An acid **dissociates** in water to produce $\ce{H+}$ ions (protons). + +A base **dissociates** in water to produce $\ce{OH-}$ ions. + +### Bronsted-Lowry theory + +The Bronsted-Lowry theory focuses on reactions with water and less the acid and base ions themselves. + +An acid is any compound that can **donate a proton ($\ce{H+}$) to water** to form a hydronium ion. +$$\ce{acid + H2O -> acid- + H3O+}$$ + +!!! info + In practice, the acid must contain a hydrogen atom attached by an easy-to-break bond (usually $\ce{H-O}$), but any high electronegativity difference polar bond would work as well. + +A base is any compound capable of **removing a proton ($\ce{H+}$) from an acid**. +$$\ce{acid + base -> acid- + base+}$$ + +!!! info + The proton usually comes from water. The base must be able to accept an $\ce{H+}$ ion to form a **dative covalent bond**, so they must contain **lone pairs**. + +#### Conjugate acids/bases + +The result of a base obtaining a proton is a **conjugate acid**. + +The result of an acid losing a proton is a **conjugate base**. + +!!! example + In the reaction + $$\ce{NH3 + H2O -> NH4+ + OH-}$$ + + $\ce{NH3}$ is a base that becomes a conjugate acid while $\ce{H2O}$ is an acid that becomes a conjugate base. + +### Louis theory + +### Strong/weak acids/bases + +### pH and pOH + ## Organic chemistry !!! definition