chem: Add acyclic nomenclature

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eggy 2021-11-24 15:09:49 -05:00
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@ -515,9 +515,14 @@ Carbon is also able to bond to itself in the following ways:
### Simple hydrocarbons
!!! definition
- A **branched hydrocarbon** is one with at least one "side group" extending from the main hydrocarbon chain.
- A **functional group** is a group of atoms responsible for the characteristic properties of a molecule (e.g. C=C)
- A **homologous series** is a family of organic compounds with the same functional group but the hydrocarbon chain length changes by 1 $\ce{CH2}$ group.
These only contain carbon and hydrogen.
**Alkanes** only contain single bonds between carbons, and are named with the number of carbons with the suffix "-ane".
**Alkanes** are a homologous series that only contain single bonds between carbons, and are named with the number of carbons with the suffix "-ane".
<img src="/resources/images/alkanes.png" width=700>(Source: Kognity)</img>
@ -566,6 +571,63 @@ A **line diagram** or **skeletal structural formula** removes carbons and hydrog
These are the ways to represent pentane, $\ce{C5H12}$. The structural formula is mislabeled as a condensed structural diagram.
<img src="/resources/images/pentane.png" width=700>(Source: Kognity)</img>
### General nomenclature
To name an organic compound:
1. Find the **longest acyclic chain** of carbon atoms as the parent chain.
2. Assign numbers from 1 to $n$ for each carbon atom in the parent chain.
- The numbers should be arranged in a way that the highest priority functional group in the chain is assigned the lowest number possible.
- Apply the **first branch rule** only if there is a tie: If there are side chains, the parent chain should be numbered such that the location of any side chains have the lowest number possible.
- If there is a tie, the location with the most branches wins.
- If there is a tie, the rest of the chain is compared in sequence applying the first branch rule.
- If there is a tie, the first location with the side chain group name that is alphabetically greater wins.
- If there is a tie, it doesn't matter which side is picked as the whole thing is symmetrical.
3. Name the main chain based on the name of the functional group and location number for the functional group in the format "number-name".
4. Name the side groups.
- If the group is not carbon, name it by its identity.
- Otherwise, name the hydrocarbon based on the number of carbons in the side group with the ending "yl".
- If there is more than one identical side group in the **whole chain**, combine their numbers and names with a Greek prefix.
- Assign a number representing the carbon atom of the parent chain that the side group is attached to in the form "numbers-name".
5. Arrange the name with each side group with their numbers in alphabetical order, discounting any prefixes due to duplicates, followed by the parent chain.
6. Join everything together:
- Drop the ending vowel from the prefix if there is a double vowel unless it is "i".
- Separate numbers from words with dashes.
- Separate numbers from numbers with commas.
- Do not separate words from words.
!!! tip
In hydrocarbons:
- Atoms with double or triple bonds share equal priority as the highest functional group.
- The main chain will be named as an alkane if there are only single bonds.
- If there is exactly one double or triple bond, it will be named as an alkene or alkyne with its position inserted between the prefix and ending.
- e.g., "pentane", "pent-2-ene"
- If there are multiple double or triple bonds, their numbers are also included, but an "a" is appended to the prefix and a Greek prefix added to the suffix.
- e.g., "penta-1,3-diene", "hexa-1,3,5-triyne"
- If there are both double and triple bonds, the "-ene" becomes "-en" and is always before "-yne".
- e.g., "pent-4-en-2-yne"
!!! example
tf
Other **side chains** with equal priority as double or triple bonds *in side chains* include:
- halogens, which have their "-ine" suffix replaced with "o" (e.g., "chloro")
- $\ce{NO2}$: "nitro-"
- benzene (as a side chain): "phenyl"
If there is no other option and there is a **branched side chain**, name it based on the total number of carbon atoms in the side chain.
!!! example
tf
### Cyclic hydrocarbons
### Isomers and functional groups
## Resources
- [IB Chemistry Data Booklet](/resources/g11/ib-chemistry-data-booklet.pdf)