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chem: Add acyclic nomenclature
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@ -515,9 +515,14 @@ Carbon is also able to bond to itself in the following ways:
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### Simple hydrocarbons
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!!! definition
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- A **branched hydrocarbon** is one with at least one "side group" extending from the main hydrocarbon chain.
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- A **functional group** is a group of atoms responsible for the characteristic properties of a molecule (e.g. C=C)
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- A **homologous series** is a family of organic compounds with the same functional group but the hydrocarbon chain length changes by 1 $\ce{CH2}$ group.
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These only contain carbon and hydrogen.
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**Alkanes** only contain single bonds between carbons, and are named with the number of carbons with the suffix "-ane".
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**Alkanes** are a homologous series that only contain single bonds between carbons, and are named with the number of carbons with the suffix "-ane".
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<img src="/resources/images/alkanes.png" width=700>(Source: Kognity)</img>
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@ -566,6 +571,63 @@ A **line diagram** or **skeletal structural formula** removes carbons and hydrog
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These are the ways to represent pentane, $\ce{C5H12}$. The structural formula is mislabeled as a condensed structural diagram.
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<img src="/resources/images/pentane.png" width=700>(Source: Kognity)</img>
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### General nomenclature
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To name an organic compound:
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1. Find the **longest acyclic chain** of carbon atoms as the parent chain.
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2. Assign numbers from 1 to $n$ for each carbon atom in the parent chain.
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- The numbers should be arranged in a way that the highest priority functional group in the chain is assigned the lowest number possible.
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- Apply the **first branch rule** only if there is a tie: If there are side chains, the parent chain should be numbered such that the location of any side chains have the lowest number possible.
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- If there is a tie, the location with the most branches wins.
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- If there is a tie, the rest of the chain is compared in sequence applying the first branch rule.
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- If there is a tie, the first location with the side chain group name that is alphabetically greater wins.
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- If there is a tie, it doesn't matter which side is picked as the whole thing is symmetrical.
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3. Name the main chain based on the name of the functional group and location number for the functional group in the format "number-name".
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4. Name the side groups.
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- If the group is not carbon, name it by its identity.
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- Otherwise, name the hydrocarbon based on the number of carbons in the side group with the ending "yl".
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- If there is more than one identical side group in the **whole chain**, combine their numbers and names with a Greek prefix.
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- Assign a number representing the carbon atom of the parent chain that the side group is attached to in the form "numbers-name".
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5. Arrange the name with each side group with their numbers in alphabetical order, discounting any prefixes due to duplicates, followed by the parent chain.
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6. Join everything together:
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- Drop the ending vowel from the prefix if there is a double vowel unless it is "i".
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- Separate numbers from words with dashes.
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- Separate numbers from numbers with commas.
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- Do not separate words from words.
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!!! tip
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In hydrocarbons:
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- Atoms with double or triple bonds share equal priority as the highest functional group.
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- The main chain will be named as an alkane if there are only single bonds.
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- If there is exactly one double or triple bond, it will be named as an alkene or alkyne with its position inserted between the prefix and ending.
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- e.g., "pentane", "pent-2-ene"
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- If there are multiple double or triple bonds, their numbers are also included, but an "a" is appended to the prefix and a Greek prefix added to the suffix.
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- e.g., "penta-1,3-diene", "hexa-1,3,5-triyne"
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- If there are both double and triple bonds, the "-ene" becomes "-en" and is always before "-yne".
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- e.g., "pent-4-en-2-yne"
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!!! example
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tf
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Other **side chains** with equal priority as double or triple bonds *in side chains* include:
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- halogens, which have their "-ine" suffix replaced with "o" (e.g., "chloro")
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- $\ce{NO2}$: "nitro-"
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- benzene (as a side chain): "phenyl"
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If there is no other option and there is a **branched side chain**, name it based on the total number of carbon atoms in the side chain.
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!!! example
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tf
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### Cyclic hydrocarbons
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### Isomers and functional groups
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## Resources
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- [IB Chemistry Data Booklet](/resources/g11/ib-chemistry-data-booklet.pdf)
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