chem: Add polymers

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eggy 2022-04-11 10:44:00 -04:00
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### Simple polymers
!!! definition
- **Polymers** are large molecules made from many monomers in long chains.
- **Plastics** are polymers formed through addition.
- A **homopolymer** has identical monomers.
- A **heteropolymer** has multiple distinct monomers.
- A **monomer** is the repeating segment in a polymer.
Polymer properties change based on the type of linkages, the presence of side chains, and the extent of crosslinking between other chains.
The **addition formation** of an **addition polymer** opens up pi bonds which are used to bond to other monomers. Monomers are continuously added until the process ends with hydrogen atoms capping the ends.
<img src="/resources/images/addition-polymer.png" width=700>(Source: Kognity)</img>
Only the two carbons directly involved in the double bond go in the main chain of the polymer, with all others expressed as side groups.
<img src="/resources/images/addition-polymer-notation.png" width=900>(Source: Kognity)</img>
**Polymer notation** is the formula/condensed formula/structural diagram of the **repeating unit only** with crossed out brackets and the number of repetitions at the bottom right (or $n$ if unknown). Side groups should be clearly expressed as side groups. Polymers are named with the prefix **poly-** on the repeating unit.
!!! example
$$\ce{-(-CH2-CH2-) -_3}$$
#### Crosslinking
!!! definition
- **Crosslinking** is the bond between side chains of separate polymers, connecting them.
The crosslinking between polymers depends on the side chains. If there are multiple double bonds in monomers, those can be used in different chains which can attach them together.
!!! example
divinylbenzene
!!! example
If an OH side group meets another OH side group, they may react to form $\ce{O=O}$ and connect the two polymers.
### Polyesters and polyamides
### Stereoisomers
!!! definition
- **Condensation polymers** are polymers formed via dehydration synthesis and produce water.
A **polyester** has monomers connected via an ester linkage on both ends. **Unlike addition polymers**, any carbons between the functional groups are included in the parent polymer chain.
<img src="/resources/images/polyester-formation.png" width=700>(Source: Kognity)</img>
The repeating unit should be **copy-pastable** — it should not end with oxygen on both ends. The link is broken where it would normally break — between the C-O of the ester linkage, such that the O goes to the side of the alcohol.
<img src="/resources/images/polyester-notation.png" width=700>(Source: Kognity)</img>
A **polyamide** has monomers connected via an amide linkage on both ends.
<img src="/resources/images/polyamide-formation.png" width=700>(Source: Kognity)</img>
!!! warning
There should be a hydrogen attached to the nitrogen at the end of the amine.
### E-Z isomers
### Optical isomers
### Properties of organic compounds