chem: Add polymers
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### Simple polymers
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### Simple polymers
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!!! definition
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- **Polymers** are large molecules made from many monomers in long chains.
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- **Plastics** are polymers formed through addition.
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- A **homopolymer** has identical monomers.
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- A **heteropolymer** has multiple distinct monomers.
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- A **monomer** is the repeating segment in a polymer.
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Polymer properties change based on the type of linkages, the presence of side chains, and the extent of crosslinking between other chains.
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The **addition formation** of an **addition polymer** opens up pi bonds which are used to bond to other monomers. Monomers are continuously added until the process ends with hydrogen atoms capping the ends.
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<img src="/resources/images/addition-polymer.png" width=700>(Source: Kognity)</img>
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Only the two carbons directly involved in the double bond go in the main chain of the polymer, with all others expressed as side groups.
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<img src="/resources/images/addition-polymer-notation.png" width=900>(Source: Kognity)</img>
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**Polymer notation** is the formula/condensed formula/structural diagram of the **repeating unit only** with crossed out brackets and the number of repetitions at the bottom right (or $n$ if unknown). Side groups should be clearly expressed as side groups. Polymers are named with the prefix **poly-** on the repeating unit.
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!!! example
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$$\ce{-(-CH2-CH2-) -_3}$$
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#### Crosslinking
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!!! definition
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- **Crosslinking** is the bond between side chains of separate polymers, connecting them.
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The crosslinking between polymers depends on the side chains. If there are multiple double bonds in monomers, those can be used in different chains which can attach them together.
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!!! example
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divinylbenzene
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!!! example
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If an OH side group meets another OH side group, they may react to form $\ce{O=O}$ and connect the two polymers.
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### Polyesters and polyamides
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### Polyesters and polyamides
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### Stereoisomers
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!!! definition
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- **Condensation polymers** are polymers formed via dehydration synthesis and produce water.
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A **polyester** has monomers connected via an ester linkage on both ends. **Unlike addition polymers**, any carbons between the functional groups are included in the parent polymer chain.
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<img src="/resources/images/polyester-formation.png" width=700>(Source: Kognity)</img>
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The repeating unit should be **copy-pastable** — it should not end with oxygen on both ends. The link is broken where it would normally break — between the C-O of the ester linkage, such that the O goes to the side of the alcohol.
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<img src="/resources/images/polyester-notation.png" width=700>(Source: Kognity)</img>
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A **polyamide** has monomers connected via an amide linkage on both ends.
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<img src="/resources/images/polyamide-formation.png" width=700>(Source: Kognity)</img>
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!!! warning
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There should be a hydrogen attached to the nitrogen at the end of the amine.
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### E-Z isomers
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### Optical isomers
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### Properties of organic compounds
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### Properties of organic compounds
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